Pallādija katalizēta 2-benzilpiridīna un hinaldīna arilēšana
Date
2008
Authors
Liepiņš, Ainārs
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Publisher
Latvijas Universitāte
Abstract
Pallādija katalizēta 2-benzilpiridīna un hinaldīna arilēšana. Liepiņš A., zinātniskais vadītājs Dr. habil. ķīm. Ābele E. Bakalaura darbs, 47 lappuses, 7 attēli, 4 tabulas, 29 literatūras avoti, 2 pielikumi. Latviešu valodā.
Darbā pētīta 2-benzilpiridīna un hinaldīna arilēšana pallādija (II) acetāta un fofsīnu ligandu katalītiskajās sistēmās. Aprakstīta difenil-(2-piridil)- un difenil-(2-hinolil)metānu un to metoksi- atvasinājumu vienpakāpes iegūšanas metode. Vielu identitāte noteikta ar 1H-KMR spektroskopijas un GH-MS analīžu metodēm.
Palladium-catalyzed arylation of 2-benzylpyridine and quinaldine. Liepiņš A., supervisor Dr. habil. chem. Ābele E. Bachelor’s thesis, 47 pages, 7 figures, 4 tables, 29 literature references, 2 appendices. In Latvian. Arylation of 2-benzylpyridine and quinaldine in various phosphines assisted catalytic systems of palladium (II) acetate has been studied. A one-step method for the preparation of diphenyl-(2-pyridyl)- and diphenyl-(2-quinolyl)methanes and their methoxy derivatives is described. The identity of the compounds has been proved by 1H-PMR spectroscopy and GC-MS.
Palladium-catalyzed arylation of 2-benzylpyridine and quinaldine. Liepiņš A., supervisor Dr. habil. chem. Ābele E. Bachelor’s thesis, 47 pages, 7 figures, 4 tables, 29 literature references, 2 appendices. In Latvian. Arylation of 2-benzylpyridine and quinaldine in various phosphines assisted catalytic systems of palladium (II) acetate has been studied. A one-step method for the preparation of diphenyl-(2-pyridyl)- and diphenyl-(2-quinolyl)methanes and their methoxy derivatives is described. The identity of the compounds has been proved by 1H-PMR spectroscopy and GC-MS.
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