2,6-Diazabiciklo[2.2.2]oktān-3,5-dionu sintēze
| dc.contributor.advisor | Zicmanis, Andris | en_US |
| dc.contributor.author | Pelšs, Jānis | en_US |
| dc.contributor.other | Latvijas Universitāte. Ķīmijas fakultāte | en_US |
| dc.date.accessioned | 2015-03-24T07:34:10Z | |
| dc.date.available | 2015-03-24T07:34:10Z | |
| dc.date.issued | 2012 | en_US |
| dc.description.abstract | 2,6-Diazabiciklo[2.2.2]oktān-3,5-dionu sintēze. Pelšs J., zinātniskie vadītāji Dr. chem., vadošais pētnieks Žalubovskis R., Grandāne A., Dr. habil. chem. prof. Zicmanis A. Bakalaura darbs, 46 lappuses, 3 attēli, 18 tabulas, 28 literatūras avoti. Latviešu valodā. Darbā ir veikta 2,6-diazabiciklo[2.2.2]oktān-3,5-dionu sintēze trīskomponentu viena reaktora reakcijā. Tika sintezēta virkne 2,6-diazabiciklo[2.2.2]oktān-3,5-dionu ar dažādiem alkil- un arilaizvietotājiem pie bicikla C-1 un C-8 atomiem. Iegūto savienojumu struktūra tika pierādīta ar KMR spektroskopiju. 2,6-Diazabiciklo[2.2.2]oktān-3,5-diona reģioizomēra bicikliskā struktūra tika apstiprināta ar rentgenstruktūranalīzi. 2,6-DIAZABICIKLO[2.2.2]OKTĀN-3,5-DIONS, TRĪSKOMPONENTU REAKCIJA, AMĪDU IEKŠMOLEKULĀRĀ CIKLIZĀCIJA. | en_US |
| dc.description.abstract | Synthesis of 2,6-diazabicyclo[2.2.2]octane-3,5-diones. Pelšs J., scientific supervisors Dr. chem., principal scientist Žalubovskis R., Grandāne A., Dr. habil. chem. prof. Zicmanis A. Bachelor’s thesis, 46 pages, 3 figures, 18 tables, 28 literature references. In this work, 2,6-diazabicyclo[2.2.2]octane-3,5-diones were synthesized by a way of a three-component one-pot reaction. A series of 2,6-diazabicyclo[2.2.2]octane-3,5-diones with a variety of subtituents at the C-1 and C-8 atoms of the bicyclic structure. The structure of the synthesized compunds was confirmed by NMR spectra. The bicyclic structure of the regioisomer of 2,6-diazabicyclo[2.2.2]octane-3,5-dione was also confimed by X-ray structure analysis. 2,6-DIAZABICYCLO[2.2.2]OCTANE-3,5-DIONE, THREE-COMPONENT REACTION, INTRA-MOLECULAR CYCLIZATION OF AMIDES. | en_US |
| dc.identifier.other | 21913 | en_US |
| dc.identifier.uri | https://dspace.lu.lv/dspace/handle/7/18857 | |
| dc.language.iso | N/A | en_US |
| dc.publisher | Latvijas Universitāte | en_US |
| dc.rights | info:eu-repo/semantics/openAccess | en_US |
| dc.subject | Ķīmija | en_US |
| dc.title | 2,6-Diazabiciklo[2.2.2]oktān-3,5-dionu sintēze | en_US |
| dc.title.alternative | Synthesis of 2,6-diazabicyclo[2.2.2]octan-3,5-diones | en_US |
| dc.type | info:eu-repo/semantics/bachelorThesis | en_US |